Season the pork chops on both sides with the paprika, garlic powder, onion powder, salt, and pepper. Set aside on a plate.
Select SAUTE or SEAR/SAUTE on your pressure cooker. Once warm, pour the olive oil into the pot. Add the pork chops and sear for about 2 minutes on each side, just until the outsides are browned. Transfer the pork to a plate and set aside.
Pour broth (or water) into the pot and use a wooden spoon to scrape up any browned bits at the bottom of the pot. Pour the rice into the pot and stir gently to submerge the rice in the liquid.
Spray two pressure cooker racks with cooking spray. Place one rack over the rice, then place two pork chops on top of the rack. Place the second rack to fit over the first, and put the two remaining chops on top. See NOTES section for tips.
Assemble the pressure lid, making sure the pressure release valve is in the SEAL position. Select PRESSURE or MANUAL, set to HI, and set the time to 6 minutes. Select START/STOP or START to begin.
The pressure cooker will take a few minutes to come to pressure, then start cooking and counting down. When cooking is complete, allow the pressure to naturally release for 6 minutes. Then after 6 minutes, do a Quick Release by moving the pressure release valve to the VENT position. Once all of the pressure has been released and the float pin has dropped down all the way, carefully open the lid.
Use tongs or oven mitts to carefully lift the racks out of the electric pressure cooker and plate the pork chops. Use a fork to fluff up the rice, and serve.
Notes
Pork: Use bone-in pork chops. If using boneless pork chops, reduce the pressure cooking time by 1 minute. Racks: You will need two racks for this recipe. If you have a Ninja Foodi, use the Deluxe Reversible Rack in the lower steam position for the first set of pork chops. Then add on the Deluxe Layer rack to use for the remaining two pork chops. If you have an Instant Pot or other electric pressure cooker, use two racks that fit inside the pot and nest on top of one another with space in-between, giving the pork chops on the bottom room to cook properly.